Litter Man
- Bio/Stats
- His complacency and "someone else can clean my mess" attitude make for a slovenly appearance.
- Third half cousin, once removed, to Mathman.
- Powers
- Using refuse he pollutes wherever possible (usually in front of Chuckman for some strange reason) and helps destroy mother nature.
- Symbol
- None.
- Disposition
- Currently on a work release program cleaning the sides of highways.
Mathman
- Bio/Stats
- Former Teacher.
- He wishes he was French (cowboy), because, "All the cool villains are French (and they get the hottest villainesses)." Because of that, he speaks with a horrible, fake, French accent, sometimes spouting nonsensical French phrases. Fights while posing as though he is fencing, which he thinks is French for some reason.
- Powers
- Using his wand he draws up complex mathematical equations (in the air), which come to life and confound Chuckman.
- Symbol
- The square root of negative one (1) (the imaginary number (i))
- Disposition
- Whereabouts unknown.
Family Of Evil (F.O.E.)
- Bio/Stats
- A Family Organization Dedicated To Evil Doings And The Combat And Eradication Of Chuckman.
- Powers
- The ability to congregate/mass in large numbers to plot the overthrow of goodness/Chuckman.
- Disposition
- Now Accepting Applications! Special considerations given to mad/evil scientists.
2-D Man
- Bio/Stats
- Twin To The Timeshifter (by different mothers).
- Founding Member of F.O.E.
- Powers
- Ability to make items 2-dimensional by removing them from the 3rd dimension.
- Symbol
- Two capital D's back to back (so it appears to be a bisected circle).
- Disposition
- Whereabouts unknown.
The Timeshifter
- Bio/Stats
- Twin To 2-D Man (by different mothers).
- Member of F.O.E.
- Powers
- Ability to shift through time at one hour intervals.
- Symbol
- The outline of an hourglass.
- Disposition
- Whereabouts unknown.
The Intoxicatetress
- Bio/Stats
- First villainess inducted into F.O.E.
- Began career of evil with theft from charity fundraiser.
- Powers
- Booming voice with concussive effects.
- Limited time distortion and mind control.
- Symbol
- XXX.
- Disposition
- Whereabouts unknown.
Grammar Woman - Mad Scientist
- Bio/Stats
- Doesn't speak English, which utterly confuses and confounds Chuckman (as well as others), but requires grammatical perfection at all times.
- Recently Graduated from California State University of Evil (C.S.U.E.) where she obtained a Bachelor's Degree in Math and Science.
- Powers
- Mind Control/Erasure
- Limited Shape Shifting/Morphing Ability.
- Symbol
- ∞ (infinity).
- Disposition
- Currently Studying Masters in Telepathy (In order to achieve evil from home, similar to telecommuting).
Lightning Guy
- Bio/Stats
- Wears a cool upper body harness that's metallic (shiny) with wings. Cannot fly.
- Lightning bolts whether stored and discharged from his body, or redirected from the heavens, obey his commands.
- Extremely distructive to home electronics.
- Powers
- Ability to throw lightning bolts.
- Symbol
- None.
- Disposition
- Currently being reeducated (raised as a son) by Chuckman.
Great Evil Pumpkin - Dr. Baron Von Fruitenstein
- Bio/Stats
- Was accidentally created by Dr. Baron Von Fruitenstein while trying to develop self-picking fruit.
- Likes Halloween (is there a future episode in store?).
- Powers
- Controls orange fruits and vegetables.
- Symbol
- Pumpkin.
- Disposition
- Currently being sought to be made into a delicious, low calorie fruit drink.